Product ID:BLACK STENCIL INK 7080, 50007080
MSDS Date:10/11/1991
FSC:7510
NIIN:00N009500
MSDS Number: BZZPQ

CROWN INDUSTRIAL PRODUCTS CO INC

STATE LINE RD
HEBRON, IL 60034
US

Emergency Phone: 800-255-3924

Info Phone: 815-648-2424

Preparer: PATRICK T PASIERB

Cage: 92381

CROWN INDUSTRIAL PRODUCTS CO

350 HEBRON, IL 60034 US

Telephone: 815-648-2424

Cage: 92381

STODDARD SOLVENT; (MINERAL SPIRITS)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 1-10%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (PROPYLENE

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 1-10%

OSHA PEL N/K

ACGIH TLV: N/K

TOLUENE (SARA 313) (CERCLA)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 11-30%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 31-50%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HYDROCARBON PROPELLANT (PROPANE/ISOBUTANE); (LIQUIFIED

CAS: 68476-86-8

Fraction By Weight: 11-30%

OSHA PEL 900 PPM (MFR)

ACGIH TLV: 900 PPM (MFR)

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: HIGH VAP CONCS MAY RSLT
IN DIZZ, HDCH/UNCON. EYE: MAY CAUSE IRRIT. POSS CORNEAL INJURY.
SKIN: PRLNG CONT WILL CAUSE DEFAT OF SKIN LEADING TO IRRIT & DERM.
SKIN ABSORPTION: NOT LIKELY TO BE ABSORBED IN TOX AMTS. CHRONIC:
TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZ. SEEK CONSULT
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONO, SUPP, VOL
7, PG 194, 1987: GROUP 2B. NTP 7TH ANNUAL REPORT ON CARCINS, 1994:
(SUP DAT)
Effects of Overexposure:HLTH HAZ:FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO.
CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAV E SIMILAR EFT IN HUMANS.
ADRENOMIMETICS(E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR
LIFE-SUSTAINING (SUP DAT)
Medical Cond Aggravated by Exposure:MAY INCREASE MYOCARDIAL
IRRITABILITY. AVOID EPINEPHRINE OR SIMILAR DRUGS IF AT ALL
POSSIBLE.

First Aid:CALL MD. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES OR
UNTIL IRRITATION SUBSIDES. SKIN: REMOVE ALL CONTAMINATED CLOTHING.
WASH SKIN WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE
IMMEDIATEL Y. IF BREATHING IS STOPPED OR IRREGULAR, BEGIN
ARTIFICIAL RESPIRATION AND ADMINISTER OXYGEN. INGESTION: DO NOT
INDUCE VOMITING. DRINK PLENTY OF WATER.

Flash Point Method:TCC
Flash Point:-50F,-46C
Lower Limits:1.8%
Upper Limits:9.5%
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TREAT AS CYLINDERS OF COMPRESSED GAS.
THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF
IGNITION. CLEAN UP WITH INERT MATERIALS AND DISPOSE OF IN
ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT, NEAR
OPEN FLAMES/AT TEMPS > 120F. DO NOT SMOKE WHILE SPRAYING. USE ONLY
AS DIRECTED.
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONC VAPS &
INHALING CONTENTS CAN BE HARMFUL/FATAL. NO SMKNG IN AREA OF USE. DO
NOT USE IN GEN VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURF. HEAT
&/UV RADIA MAY CAU SE FORMATION OF HCL &/PHOSGENE .

Respiratory Protection:RESPIRATORY PROTECTION PROGRAM SHOULD BE IN
ACCORDANCE WITH 29 CFR 1910.134. USE NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST IS ADEQUATE.
Protective Gloves:POLYETHYLENE OR NEOPRENE.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS .
Other Protective Equipment:PROT CLTHG & EQUIP: SEE 29 CFR 1910.133 &
132. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA
.
Work Hygienic Practices:WASH SKIN WITH SOAP AND WATER.
Supplemental Safety and Health
EFTS OF OVEREXP: USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO
CHLOROCARBONS . CARCIN EXPLAN: ANTIC TO BE CARCIN. ANIMAL: LUNG,
SALIVARY, MAMMARY GLAND (TUMORS).

Vapor Pres:45-50 PSIG
Vapor Density:>1
Spec Gravity:>1
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK, WITH ETHEREAL ODOR
Percent Volatiles by Volume:98

Stability Indicator/Materials to Avoid:YES
ALKALI METALS, MINERAL ACIDS.
Stability Condition to Avoid:OPEN FLAMES, SPARKS, ELECTRICAL SPARK
SOURCES.
Hazardous Decomposition Products:THERMAL DECOMP MAY YIELD SML AMTS OF
HALOGEN ACIDS, CARBON MONOXIDE & OTHER TOX CHEMICALS. HCL, PHOGENE
.

Waste Disposal Methods:DO NOT PUNCTURE OR INCINERATE. EMPTY CONTAINERS
MAY BE DISPOSED OF THROUGH NORMAL CHANNELS. FULL/PARTIALLY FILLED
CONTAINERS ARE CONSIDERED HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE
W/LOCAL, STATE & F EDERAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.